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Liquid Fuels
*** Shopping-Tip: Liquid Fuels
'''Liquid fuels''' are those combustible or energy-generating molecules which can be harnessed to create
mechanical energy, usually producing
kinetic energy, and which also must take the shape of their container. Most liquid fuels in widespread use are or are dervied from
fossil fuels; however, there are several types, such as hydrogen fuel (for
automotive use), that are also categorized as liquid fuels.
This article deals primarily with the concept of liquid fuels in relation to ground transport. However, others such as
rocket fuel also play an important role in the economy.
Fossil fuels
''Main Article:
Fossil Fuel''
'''Fossil fuels''' which are also liquid fuels come from dead animals and plants which died many millions of years ago. The most notable of these is
gasoline.
Gasoline
''Main Article:
Gasoline''
'''Gasoline''' is the most widely used liquid fuel. Gasoline, as it's known in United States and Canada, (known as '''petrol''' in Britain, Australia, New Zealand, and many English-speaking countries) is made of hydrocarbon
molecules forming
aliphatic compounds, or chains of carbons with hydrogen atoms attached. However, many
aromatic compounds (carbon chains forming rings) such as
benzene are found naturally in gasoline and cause the health risks associated with prolonged exposure to the fuel.
Production of gasoline is achieved by
distillation of
crude oil. The desirable liquid is separated from the crude oil in
refineries. Crude oil is extracted from the ground in several processes, the most commonly seen may be
beam pumps. To create gasoline,
petroleum must first be removed from crude oil.
Gasoline itself is actually not burned, but the fumes it creates ignite, causing the remaining liquid to
evaporate. Gasoline is extremely volatile and easily combusts, making any leakage extremely dangerous. Gasoline for sale in most countries carries an
octane rating. Octane is a measure of the resistance of gasoline to combusting prematurely, known as
engine knocking knocking. The higher the octane rating, the harder it is to burn the fuel, which allows for a higher
compression ratio. Engines with a higher compression ratio produce more power (such as in race car engines). However, such engines actually ''require'' a higher octane fuel.
Diesel
''Main Article:
Diesel''
Conventional '''diesel''' is similar to gasoline in that it is a mixture of aliphatic hydrocarbons extracted from petroleum. Diesel may cost more or less than gasoline, but generally costs less to produce because the extraction processes used are simpler. Many countries (particularly in Europe) also have lower tax rates on diesel fuels.
After distillation, the diesel fraction is normally processed to reduce the amount of
sulfur in the fuel. Sulphur causes corrosion in vehicles,
acid rain and higher emissions of soot from the tail pipe (exhaust pipe). In Europe, lower sulfur levels than in the United States are legally required. However, recent US legislation will reduce the maximum sulphur content of diesel from 3,000 ppm to 500 ppm by 2007, and 15 ppm by 2010. Similar changes are also underway in Australia, New Zealand and several Asian countries.
A
diesel engine is a type of
internal combustion engine which ignites fuel by compressing it (which in turn raises the temperature) as opposed to using an outside source, such as a spark plug.
Alcohols
Alcohols are a useful type of liquid fuel because they combust rapidly (too rapidly for fossil fuel replacement) and are often cheap to produce. However, their acceptance is hampered by the fact that their production often requires as much or even more fossil fuel than they replaced. In this sense, alcohols are a chemical substance; they are similar chemically, but not identical to, the
depressant of the same name (
alcoholic beverages).
Butanol
''Main Articles:
Butanol,
Clostridium acetobutylicum,
alcohol as a fuel''
'''Butanol''' is an
alcohol which may be used as a fuel with the normal combustion engine, typically as a product of the
ferment of
biomass with the
bacterium ''clostridium acetobutylicum'' (also known as the Weizmann organism). This process was first delineated by
Chaim Weizmann in
1916 for the production of
acetone from
starch for making
trinitrotoluene TNT.
The advantages of butanol are its high octane rating (over 100) and high energy content, only about 10% lower than gasoline, and subsequently about 50% more energy-dense than ethanol, 100% more so than methanol. Butanol's only major disadvantages are its high flashpoint (95 °F or 35 °C), toxicity (note that toxicity levels exist but are not precisely confirmed to my knowledge), and the fact that the fermentation process for renewable butanol emits a foul odour. NOTE: Making butanol from oil produces no such odour, but the limited supply and environmental impact of oil usage defeats the purpose of alternative fuels. The cost of butanol is about $0.57-$0.58 per pound ($1250-$1320 per ton or $8 approx. per gallon) - so another drawback is its high cost in proportion to ethanol (approx. $1.50 per gallon) and methanol.
Ethanol
''Main Article:
Ethanol,
Ethanol fuel''
'''Ethanol''', also known as grain alcohol or ethyl alcohol, is most commonly used in
alcoholic beverages. However, it may also be used as a fuel, most often in combination with gasoline. For the most part, it is used in a 9:1 ratio of gasoline to ethanol to reduce the negative environmental effects of gasoline.
There is increasing interest in the use of a blend of 85% fuel ethanol blended with 15% gasoline. This fuel blend called E85, has a higher fuel octane than premium gasoline, allowing in properly optimized engines increases in both power and fuel economy over gasoline. When used in modern FFV (flexible fuel vehicles) it delivers preformance similar to the gasoline it replaces. [http://en.wikipedia.org/wiki/E85]
Ethanol for use in gasoline and industrial purposes may be called a fossil fuel because it is synthesised from the petroleum product
ethylene, which is cheaper than production from
fermentation of
cereal grains or
sugarcane.
Methanol
''Main Article:
Methanol,
Methanol fuel''
'''Methanol''' is the lightest and simplest
alcohol, produced from the
natural gas component
methane. Its application is limited due to its toxicity. Small amounts are used in some gasolines to increase the
octane rating. Methanol-based fuels are used in some race cars and model airplanes.
Methanol is also called ''methyl alcohol'' or ''wood alcohol'', the latter because it was formerly produced from the
distillation of wood.
Hydrogen
''Main Article:
Hydrogen car''
'''
Hydrogen''' as a fuel is a feasible option for future use as a fuel. Liquid hydrogen is an important consideration because it has a higher density than its gaseous counterpart. Liquid hydrogen would be stored in cryogenic tanks. Its application would be most useful in
fuel cells where hydrogen would react with oxygen (obviously this is readily available in the air) to create electricity which would power the vehicle.
Unfortunately, widespread use of liquid hydrogen is several decades away. Their application is plagued with several serious problems including production, which may still involve fossil fuels, durability of the fuel cells to common roadway conditions such as bumps, the impracticability of conversion of older cars and difficulties with storage and handling. For a more detailed explanation see the
Hydrogen car article.
See also
*
Rocket fuel
*
E85
Category:Fuels
see
Liquid fuels
*** Shopping-Tip: Liquid Fuels